Preparation of Elastomeric Nanocomposites Using Nanocellulose and Recycled Alum Sludge for Flexible Dielectric Materials

Sun, Dongyang; Saw, Bernard L.H.; Onyianta, Amaka J.; Wang, Bowen; Wilson, Callum; O'Rourke, Dominic; See, Chan H.; Popescu, Carmen-Mihaela; Dorris, Mark; Shyha, Islam; Lu, Zhilun

Abstract

Flexible dielectric materials with environmental-friendly, low-cost and high-energy density characteristics are in increasing demand as the world steps into the new Industrial 4.0 era. In this work, an elastomeric nanocomposite was developed by incorporating two components: cellulose nanofibrils (CNFs) and recycled alum sludge, as the reinforcement phase and to improve the dielectric properties, in a bio-elastomer matrix. CNF and alum sludge were produced by processing waste materials that would otherwise be disposed to landfills. A biodegradable elastomer polydimethylsiloxane was used as the matrix and the nanocomposites were processed by casting the materials in Petri dishes. Nanocellulose extraction and heat treatment of alum sludge were conducted and characterized using various techniques including scanning electron microscopy (SEM), thermogravimetric analysis/derivative thermogravimetric (TGA/DTG) and X-ray diffraction (XRD) analysis. When preparing the nanocomposite samples, various amount of alum sludge was added to examine their impact on the mechanical, thermal and electrical properties. Results have shown that it could be a sustainable practice of reusing such wastes in preparing flexible, lightweight and miniature dielectric materials that can be used for energy storage applications.

Citation

Sun, D., Saw, B. L., Onyianta, A. J., Wang, B., Wilson, C., O'Rourke, D., See, C. H., Popescu, C., Dorris, M., Shyha, I., & Lu, Z. (2023). Preparation of Elastomeric Nanocomposites Using Nanocellulose and Recycled Alum Sludge for Flexible Dielectric Materials. Journal of Advanced Dielectrics, 13(01), Article 2242008. https://doi.org/10.1142/s2010135x22420085

• Journal Article Type: Article
• Acceptance Date: Nov 7, 2022
• Online Publication Date: Dec 7, 2022
• Publication Date: 2023-02
• Deposit Date: Nov 11, 2022
• Publicly Available Date: Feb 14, 2023
• Journal: Journal of Advanced Dielectrics
• Print ISSN: 2010-135X
• Electronic ISSN: 2010-1368
• Publisher: World Scientific Publishing
• Peer Reviewed: Peer Reviewed
• Volume: 13
• Issue: 01
• Article Number: 2242008
• DOI: https://doi.org/10.1142/s2010135x22420085
• Keywords: Nanocellulose, biodegradable, sustainable, alum sludge, nanocomposite, flexible, dielectric
• Public URL: http://researchrepository.napier.ac.uk/Output/2952770