A Comprehensive Analysis of Eco-Friendly Cs2SnI6 Based Tin Halide Perovskite Solar Cell through Device Modeling

Pal, Debashish

Abstract

The choice of appropriate materials is of paramount importance in realizing a high efficiency perovskite solar cell. Lead free eco-friendly perovskite solar cell architecture is theoretically investigated using solar cell capacitance simulator (SCAPS) for device performance. Preliminary investigations on Cs2SnI6solar cell architectures have indicated that the presence of hole transport layer is crucial in achieving an open-circuit voltage greater than 0.6 V. The presence of a valence band offset between the Cs2SnI6absorber and hole transport layer has a significant detrimental impact on the short-circuit current density and fill factor of the cell. A novel device architecture employing TiO2as an electron transport material and Cu2Oasahole transport material is proposed to overcome the limitations associated with the current designs. Theoretical investigations are carried out employing1D SCAPS simulation program in order to optimize the structure by varying the perovskite thickness, bandgap, and defect concentration. The proposed solar cell after optimization has a practically realizable power conversion efficiency of 17.77%.

Citation

Pal, D. (2023). A Comprehensive Analysis of Eco-Friendly Cs2SnI6 Based Tin Halide Perovskite Solar Cell through Device Modeling. Advanced Theory and Simulations, 6(3), Article 2200856. https://doi.org/10.1002/adts.202200856

• Journal Article Type: Article
• Acceptance Date: Jan 5, 2023
• Online Publication Date: Jan 26, 2023
• Publication Date: 2023-03
• Deposit Date: Feb 13, 2023
• Publicly Available Date: Feb 13, 2023
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 6
• Issue: 3
• Article Number: 2200856
• DOI: https://doi.org/10.1002/adts.202200856
• Keywords: Cs2SnI6, double halide perovskite, nonradiative recombination, perovskite solar cell, SCAPS