Md Sariful Sheikh
High Open-Circuit Voltage in Double Perovskite Oxide A2NdSbO6 (A= Ba, Sr) Photoanode-Based Dye-Sensitized Solar Cells
Sheikh, Md Sariful; Ghosh, Abyay; Roy, Anurag; Bhandari, Shubhranshu; Sundaram, Senthilarasu; Mallick, Tapas K.; Ghosh, Haranath; Sinha, T.P.
Authors
Abyay Ghosh
Anurag Roy
Shubhranshu Bhandari
Prof Senthil Sundaram S.Sundaram@napier.ac.uk
Visiting Professor
Tapas K. Mallick
Haranath Ghosh
T.P. Sinha
Abstract
Dye-sensitized solar cell (DSSC) technology, with its low-cost simple fabrication process and promising photovoltaic performance, has become a potential candidate for solar energy conversion. Recently, perovskite oxide-based photoanodes, with the potential to overcome the low photovoltage limitation in DSSCs and with easily tunable optoelectronic properties, have drawn significant research interest. In this work, an inorganic family of double perovskite oxides (DPOs), A(2)NdSbO(6) (A = Ba, Sr), possessing more flexibility in structural and electronic properties than the perovskite oxides, is introduced as a promising DSSC photoanode material. The experimental band gaps of Ba2NdSbO6 and Sr2NdSbO6 are 3.40 eV and 3.78 eV, respectively, which are close to that of TiO2. The DSSC devices fabricated using the synthesized DPO photoanodes show an exceptionally high open-circuit voltage (> 0.8 V). Finally, the density functional theory calculations using the generalized gradient approximation with Hubbard potential (GGA+U) method are performed to understand the correlation between the electronic structure and the observed high photovoltage in these DPOs.
Citation
Sheikh, M. S., Ghosh, A., Roy, A., Bhandari, S., Sundaram, S., Mallick, T. K., Ghosh, H., & Sinha, T. (2022). High Open-Circuit Voltage in Double Perovskite Oxide A2NdSbO6 (A= Ba, Sr) Photoanode-Based Dye-Sensitized Solar Cells. Journal of Electronic Materials, 51, 4281-4287. https://doi.org/10.1007/s11664-022-09681-w
Journal Article Type | Article |
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Acceptance Date | Apr 27, 2022 |
Online Publication Date | May 15, 2022 |
Publication Date | 2022-08 |
Deposit Date | Jun 28, 2022 |
Print ISSN | 0361-5235 |
Publisher | Institute of Electrical and Electronics Engineers |
Peer Reviewed | Peer Reviewed |
Volume | 51 |
Pages | 4281-4287 |
DOI | https://doi.org/10.1007/s11664-022-09681-w |
Keywords | Double perovskite oxide, optical properties, DSSC photoanode, open-circuit voltage |
Public URL | http://researchrepository.napier.ac.uk/Output/2874140 |
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