The Performance of CH3NH3PbI3 - Nanoparticles based – Perovskite Solar Cells Fabricated by Facile Powder press Technique

Pitchaiya, Selvakumar; Natarajan, Muthukumarasamy; Santhanam, Agilan; Asokan, Vijayshankar; Madurai Ramakrishnan, Venkatraman; Selvaraj, Yuvaraj; Yuvapragasam, Akila; Rangasamy, Balasundaraprabhu; Sundaram, Senthilarasu; Velauthapillai, Dhayalan

Abstract

Here, we have introduced a facile solid-state route assisted method to prepare CH3NH3PbI3 perovskite nanoparticles (PNs) and together with a facile - powder press technique, for the deposition of prepared PNs - a solution cum vacuum-free route. The perovskite layer was prepared using different lead iodide (PbI2) precursor molar concentrations (0.5, 1, 1.5, 2 mmol) and the PbI2 concentration was found to have a significant impact on the structural, optical, morphological and electrical properties. The sample prepared using molar ratio PbI2: MAI at 1:3 shows the optimal bandgap value (∼1.51 eV), broader band edge peak at 755 nm and found have good optical property for photovoltaic (PV) applications. The J–V performance of the fabricated perovskite device with FTO/c-TiO2/mp-TiO2/Perovskite/CuI/ Cr/Pt-coated FTO counter electrode has been studied. The device fabricated using the concentration at PbI2:MAI 1:3 achieved a PCE of 3.9% and resulted in better long-term stability with deterioration in η and VOC by 27.87% and 29.23% after 15 days.

Citation

Pitchaiya, S., Natarajan, M., Santhanam, A., Asokan, V., Madurai Ramakrishnan, V., Selvaraj, Y., …Velauthapillai, D. (2018). The Performance of CH3NH3PbI3 - Nanoparticles based – Perovskite Solar Cells Fabricated by Facile Powder press Technique. Materials Research Bulletin, 108, 61-72. https://doi.org/10.1016/j.materresbull.2018.08.022

• Journal Article Type: Article
• Acceptance Date: Aug 14, 2018
• Online Publication Date: Aug 31, 2018
• Publication Date: 2018-12
• Deposit Date: Feb 2, 2022
• Journal: Materials Research Bulletin
• Print ISSN: 0025-5408
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 108
• Pages: 61-72
• DOI: https://doi.org/10.1016/j.materresbull.2018.08.022
• Public URL: http://researchrepository.napier.ac.uk/Output/2840001