Nad�ge Ferlin
Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes
Ferlin, Nad�ge; Courty, Matthieu; Gatard, Sylvain; Spulak, Marcel; Quilty, Brid; Beadham, Ian; Ghavre, Mukund; Hai�, Annette; K�mmerer, Klaus; Gathergood, Nicholas; Bouquillon, Sandrine
Authors
Matthieu Courty
Sylvain Gatard
Marcel Spulak
Brid Quilty
Ian Beadham
Mukund Ghavre
Annette Hai�
Klaus K�mmerer
Nicholas Gathergood
Sandrine Bouquillon
Abstract
Ionic liquids with natural organic derived anions (l-lactate, l-tartrate, malonate, succinate, l-malate, pyruvate, d-glucuronate, d-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H2 pressure.
Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed
Citation
Ferlin, N., Courty, M., Gatard, S., Spulak, M., Quilty, B., Beadham, I., Ghavre, M., Haiß, A., Kümmerer, K., Gathergood, N., & Bouquillon, S. (2013). Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes. Tetrahedron, 69(30), 6150-6161. https://doi.org/10.1016/J.tet.2013.05.054
| Journal Article Type | Article |
|---|---|
| Publication Date | 2013-07 |
| Deposit Date | Apr 3, 2014 |
| Print ISSN | 0040-4020 |
| Publisher | Elsevier |
| Peer Reviewed | Peer Reviewed |
| Volume | 69 |
| Issue | 30 |
| Pages | 6150-6161 |
| DOI | https://doi.org/10.1016/J.tet.2013.05.054 |
| Keywords | Ionic liquids; Synthesis; Characterization; Hydrogenation; Toxicity; Biodegradation; |
| Public URL | http://researchrepository.napier.ac.uk/id/eprint/6737 |
| Publisher URL | http://dx.doi.org/10.1016/J.tet.2013.05.054 |