Study on photoelectrochemical solar cells of nanocrystalline Cd0. 7Zn0. 3Se-water soluble conjugated polymer

Chavhan, S.D.; Mane, R.S.; Lee, Wonjoo; Senthilarasu, S.; Han, Sung-Hwan; Lee, J.; Lee, Soo-Hyoung

Abstract

Cadmium zinc selenide (Cd0.7Zn0.3Se) nanocrystalline thin films were chemically synthesized onto indium tin oxide (ITO)-coated glass substrate at relatively low temperature (<90 °C). The as-deposited films were annealed in air at 200, 300, and 400 °C for 60 min. The structure and surface morphology of the films were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The water-soluble conjugated polymer, poly(2-ethynyl-N-carboxy-propyl-pyridinium bromide) (LM3), with quaternary pyridinium salts was layered by dipping the as-deposited and annealed Cd0.7Zn0.3Se films in the aqueous polymer solution. This hybrid photoanode system was subjected to photoelectrochemical (PEC) study under a light illumination intensity of 80 mW/cm2.

Citation

Chavhan, S., Mane, R., Lee, W., Senthilarasu, S., Han, S.-H., Lee, J., & Lee, S.-H. (2009). Study on photoelectrochemical solar cells of nanocrystalline Cd0. 7Zn0. 3Se-water soluble conjugated polymer. Electrochimica Acta, 54(11), 3169-3175. https://doi.org/10.1016/j.electacta.2008.11.065

• Journal Article Type: Article
• Acceptance Date: Nov 24, 2008
• Online Publication Date: Dec 9, 2008
• Publication Date: Apr 15, 2009
• Deposit Date: Mar 13, 2023
• Journal: Electrochimica acta
• Print ISSN: 0013-4686
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 54
• Issue: 11
• Pages: 3169-3175
• DOI: https://doi.org/10.1016/j.electacta.2008.11.065
• Keywords: Cd0.7Zn0.3Se, Pyridinium salt, Thin films, Photoelectrochemical solar cell
• Public URL: http://researchrepository.napier.ac.uk/Output/3036771