All Outputs (3)

Comparison of Calibration Methods for the Monitoring of a Fluorobenzene Batch Reaction Using Low-Field 19F NMR, 1H NMR, NIR, and Raman Spectrometries (2002)
Journal Article
Nordon, A., Meunier, C., McGill, C. A., & Littlejohn, D. (2002). Comparison of Calibration Methods for the Monitoring of a Fluorobenzene Batch Reaction Using Low-Field 19F NMR, 1H NMR, NIR, and Raman Spectrometries. Applied Spectroscopy, 56(4), 515-520. https://doi.org/10.1366/0003702021954971

The suitability of different process spectrometry techniques has been assessed, in terms of calibration requirements, accuracy, and precision, for the at-line monitoring of the sulfonation of fluorobenzene. Partial least-squares (PLS) calibration was... Read More about Comparison of Calibration Methods for the Monitoring of a Fluorobenzene Batch Reaction Using Low-Field 19F NMR, 1H NMR, NIR, and Raman Spectrometries.

Evaluation of Low-Field Nuclear Magnetic Resonance Spectrometry for At-Line Process Analysis (2002)
Journal Article
Nordon, A., McGill, C. A., & Littlejohn, D. (2002). Evaluation of Low-Field Nuclear Magnetic Resonance Spectrometry for At-Line Process Analysis. Applied Spectroscopy, 56(1), 75-82. https://doi.org/10.1366/0003702021954241

A low-field medium-resolution NMR spectrometer, with an operating frequency of 29 MHz for 1H, has been developed for use in process analysis. The information that is attainable at this field strength has been investigated with the use of samples from... Read More about Evaluation of Low-Field Nuclear Magnetic Resonance Spectrometry for At-Line Process Analysis.

Comparison of in-line NIR, Raman and UV-visible spectrometries, and at-line NMR spectrometry for the monitoring of an esterification reaction (2002)
Journal Article
McGill, C. A., Nordon, A., & Littlejohn, D. (2002). Comparison of in-line NIR, Raman and UV-visible spectrometries, and at-line NMR spectrometry for the monitoring of an esterification reaction. Analyst, 127(2), 287-292. https://doi.org/10.1039/b106889j

In-line Raman, near infrared and UV-visible spectometries, and at-line low-field NMR spectrometry have been used to monitor the acid-catalysed esterification of crotonic acid and butan-2-ol. Repeat reactions were carried out in a 1 L batch reactor. S... Read More about Comparison of in-line NIR, Raman and UV-visible spectrometries, and at-line NMR spectrometry for the monitoring of an esterification reaction.